Combining the catalytic enantioselective reaction of visible-light-generated radicals with a by-product utilization system† †Electronic supplementary information (ESI) available: Characterization data and experimental procedures. CCDC 1547314–1547316. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc02621h Click here for additional data file. Click here for additional data file.

Light sources and emission spectra of the lamps ............................................................................................. S2 2. Modifications for the Synthesis of Λ/Δ-RhO ...................................................................... S4 3. Synthesis of Substrates .......................................................................................................... S6 4. General Procedure ................................................................................................................. S15 5. Screening of Reaction Conditions ..................................................................................... S16 6. Mechanistic Studies ............................................................................................................... S18